Valkyria Chronicles for starters. I'm a huge fan of the game so i'll be interesting seeing how it'll turn out. Apart from that we have Shangri-La and Pandora Hearts. A usual i'll try to check everything out and then decide what i'll stick with, what i won't watch and what i'll marathon at a later date.
I have a few other avatars ready for when 00 ends.
& yes the soundtrack and complete best are well worth it. I've been listened to Kaoru Wada's scores for well over 15 years now, and this has to be one of his best works to date. Good thing you've ordered the Complete Best CD. Features two of the best Kaoru Wada pieces --- Paradise lost and LUNA.