I <3 One Piece's soundtrack! It's my favorite of all time at the moment. I just love how it's all orchestral... Plus unlike other anime, I don't find a single song played to be annoying.
(I'm just going to have to hope that the download link in these YouTube videos is no longer working. I don't know if it is or not, I've never downloaded any of these songs. But I'm going to assume so because these are quite old.)
These are my favorites!
Uunan and The Stone Storage Room
This piece stuck out to me from the very first time it was played.
To The Grand Line
No explanation needed, right?
Bet Your Life On It
Always loved this one. It's so beautiful and emotional.
I'm Here With You Too
Played during my favorite part of the series altogether so far.
Pirate 3
Just fits the mood when it's played.
Message from Uunam
Starts out kind of weird, but then it turns really pretty!
Gold and Oden
Everybody will recognize this one. lol. I also really like the second part of it with the oboe.
Landing At Town
This one has a few different pieces in it. I like all of the them. But my favorite is the third part.
There are so many other great pieces that I could list... There are A TON in fact. But I'll stop there. As I said earlier I just love how the BGM here is a real orchestra, it just adds to the anime. I also love how you get all of the instruments playing out at various times!
Edit: Fixed one broken link.