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I say Touma can block anything whose origin is within the realm of "supernatural". However, I'm fairly certain he can't stop natural phenomena. So for instance, if a building falls on him, he's screwed.
I don't know if Touma could stop railgun. Depends on whether its motion while in flight is still influenced by Mikoto's power or not. My guess is that Touma could stop any electrical interference (by that I mean any additional acceleration that Mikoto could possibly apply to the object in motion), but not the momentum of the object itself. So if she fired, say, a 500 yen coin at him a sub-sonic speeds, it would hurt. A lot.
Unless plot-kai gets involved then screw it.
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