I've got a CS6 Suite myself. The Media Encoder is really useful as you can allow something to render (usually in Premiere) as you work on something else. It also saves lost data should your actual program crash during the rendering.
Aside from that, the layouts and whatnot just look more sleek, but if you're not pumping some great hardware into productions it might not be necessary to switch. In either case, if you're on CS3 still, CS6 upgrade might be worthwhile.
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