That is a fairly old processor since the AMD you have is made in 2006. It should handle the older games, but it's not going to handle the very intensive ones.
Your CPU barely meets the minimum requirement for running GTA4 which requires a 2.4 GHz Athlon X2 and yours is 2.2 GHz, but the game should still run fine, but a little slower and you may not be able to upgrade your CPU since the newer CPUs won't support your motherboard.
However, you may not be able to play CPU intensive games like Crysis that well since your CPU is a little outdated and Crysis is very demanding on the CPU, but most games should work fine, especially the non-demanding games.
Your 4400 may be overclockable, but you have to keep in mind that overclocking will produce extra heat and can damage your hardware if you don't have proper cooling, so it's not recommended.
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