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if you listen very carefully in the last eps of mai otome you will hear sergei call the pearl otome that came to see him ****-kun.
According to wiki -kun is generally only used when talking to males...... however the text included belows does state that girls can be called -kun in rare circumstances.
-Kun is an informal and intimate honorific primarily used by superiors in addressing inferiors, or by males of roughly the same age and status in addressing each other. In some circumstances, young women may also be addressed as -kun, but almost exclusively in business settings by older male superiors. Schoolteachers typically address male students using -kun, while female students are addressed as -san. -Kun is also used among friends of similar social standing, and by parents and relatives to address older male children (instead of -chan)
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