Nanoha has more firepower than most Transformers, she can fly, and she is a considerably smaller target.
You'd need to pit her against Trypticon or the original Scorponok (the one that turns into a small battle fortress) in order to give her an honest challenge, because they have enough armor to take more than one Divine Buster, and they have enough on-board turrets to have a chance of hitting her.
Transformers would slaughter the rank-and-file TSAB soldiers, but would be outmatched by the Aces.
Of course, the Transformers would also outnumber the Aces, and two regular Decepticons could potentially overwhelm a single Ace, but the TSAB as a whole would vastly outnumber the Decepticons, leaving fewer of them to focus on the Aces.
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