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She was afraid because her powers never worked on him before, this is why she was surprised when her attacks worked on him in the bridge during the Sisters arc.
Later during the Daihaisei was angry because her powers didn't worked on him and later was suprised, again, when a single punch of her worked on Touma.
Is just she has no idea about what is the Imagine Breaker. She even thinks he is ESP, making her to think that his attacks never would work on the strongest esper, Accelerator(during the Sisters arc).
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