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Neji is nothing compared to Itachi when he killed off the Uchiha clan. No one shown so far can compare to Itachi's strength, and I question if even Sandaime in his prime could stand toe-to-toe with Itachi now. Then again, we do not know much about either's abilities. We know Itachi is feared by Oro.. and that the jounin of Kohona do not even stand the slightest chance against him. All we know about Sandaime in his prime is that he was the strongest Hokage ever, and that is not to say he was the strongest ninja.
When it all boils down, Neji is a genius but he is not at the freaky genius level of Itachi.
In closing: Itachi > All
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