Female Leads:
Shakugan no Shana (1st season is good, 2nd season sucks, 3rd season is good again.)
Blood C (Only saw the first few episodes, a little bloody for my tastes.)
A Certain Scientific Railgun (Excessive "fanservice" but still a decent story, perhaps you ought to check out the manga if you don't like the anime)
Soul Eater (Excessive fanservice in the first 3 or 4 episodes. Mostly disappears after that.)
Chrono Crusade
Read Or Die (The OVA series)
Rinne no Lagrange (Haven't seen)
Fate/zero (Haven't seen)
Male Lead but with significant female fighters:
Chrome Shelled Regios Some good female characters to go along with the male lead.
Neon Genesis Evangelion Classic anime, has several very strong female characters.
Fate Stay Night (Haven't seen)
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Cross Game - A Story of Love, Life, Death - and Baseball. What more could you want?
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