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She doesn't have auto-reflect, but in theory it shouldn't be hard for her to set herself to stop a projectile via magnetism. In fact, I think she can incinerate something that is coming at her via the heat from an electrical discharge... as (I think) she did with the ceramic explosive Frenda tried to use on her.
Basically, Mikoto is way, way more hax than she lets on. In theory she should be able to insta-kill even Accelerator from a distance by completely changing the oxygen to ozone in the area around him (if the 10032 could do this to a fair degree of effectiveness, and Misaka is over 1000 times stronger than her...) I doubt she would consider something so horribly fatal though. For all her boasts and pride, Mikoto is fundamentally different from the rest of the crazy espers who actually do kill people with their powers. She's inventive, but she doesn't have a murderer's mind (like, say, Accelerator or Mugino). Her naivete and lack of battle-to-the-death experience in a setting where she can't afford to be merciful is her biggest weakness.
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