I don't think there's anyone in bleach that really deserves to die except maybe Aizen for what he did to the vaizard group. And I don't think there's anyone who's death will propel any of the main characters' development, except maybe Byakuya for the development of Rukia but that's not happening in a million years unless Kubo wants to be the first to die to a horde of rampaging fangirls.
So imo there's isn't anyone who's death will serve a purpose yet.
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