Wrong place to post, but I'll be nice:
I do not know how it is released in your country, but the DVD-Box that I own (
http://www.evangelion.co.jp/) is in the following order:
Disc 1: Ep. 1-4
Disc 2: Ep. 5-8
Disc 3: Ep. 9-12
Disc 4: Ep. 13-16
Disc 5: Ep. 17-20
Disc 6: Ep. 21 (TV version), 21' (VHS/LD version), 22 (TV version), 22' (VHS/LD version)
Disc 7: Ep. 23 (TV version), 23' (VHS/LD version), 24 (TV version), 24' (VHS/LD version)
Disc 8: Ep. 25 and Ep. 26
Disc 9: EVANGELION: DEATH(TRUE)^2
Disc 10: THE END OF EVANGELION