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the dress of Index is the a sacred garment for a sister plus it's magical armor called walking church with pope level defense though it's destroyed by Touma but still she was a nun so she needs to wear it and here asking on what episode you are already?
If your asking in the past when she was running away from the so called magicians that are after her which was given to her by necesarius as a defense mechanism or idea in planted on her so she will continues to run away and making it hard to catch her. It's easier to catch a non-moving thing than a moving one. Plus if it's in the even that before the walking church was destroyed then even if Index is running around. A normal magician won't be even hurt her because it can even survive an attack of a saint or being in sun for 3 days or is it 3 hours.
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