Too many zanpaku-tos too little patience to quote all . So I will quote only Benihime (karunaihime) of Geta Boshi
1st shikai release nOkiro(awaken) - Change of shape
2nd shikai release Nake (cry)- Blood mist sheild
There has to be a third release in shikai form as Benihime is like Rukia's and Byakuya's zanpaku-tos
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