Very first "yeah, I'd marry her" anime character ... easy call:
Motoko Aoyama from Love Hina (kendo girl for those less familiar). That was one of the earliest series I encountered in my foray into modern anime. My earlier anime adventures ('60s and early '90s), no one got my attention at all.
Most of my favorites fall into two types: variations on her type (e.g. Mai/Kanon, Sakaki/AzuDa, Balsa/Moribito, and even Kagami/L*S or Mio/K-On!). The other type is the small tsundere (e.g. Taiga/TD, Hazuki/TMP, Togame/Katanagatari, and yeah my wife).
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