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Awakening, if I remember correctly, requires something akin to an epiphany, or a change of mentality.
Mikoto really can't have one of those, at the very least, not one that will matter enough to make her awaken.
Kakine and Accelerator are the only ones who have the potential to awaken. Though I wouldn't be surprised if Sugiita Gunha (#7) may be able to have a power increase comparable to an esper's awakening, once he figures out how his powers work, considering that Ollerus said that if Gunha figured out what the heck his powers are, than Gunha may be able to beat him.......and Ollerus is one of the strongest people in the series.
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