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Too bad about female character part because Yomi from Ga-Rei Zero would fit nicely.
Another great female character would be Homura from Mahou Shoujo Madoka★Magica. Both series and characters are awesome, you really are restricting yourself.
You can try Aoi Bungaku Series whih are set of mini stories, some could be of your liking.
Baccano! has a lot of psycho characters.
Naru from Ghost Hunt could work.
Hundred Stories, the main guy is not what you want but animation is dark/weird and disturbing just like some episodes so worth a check.
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