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Touma's been a target practice of biribiri way before that's why when they first met when he has no memories of her. His IB just automatically cancels it. Maybe due to experience and as for accelerator the "reflect" status is automatic and even in speed of light as long as it enters the AIM field its deflected "BUT" that only occurs to past attacks. If you attack him with a new weapon that surpass the speed of light that accelerator hasn't seen yet so far then its a chance that its not been programed yet to reflect.
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