Probably when she figures out on his meeting Rin and Luvia and their reactions to him.
In this version she is 11 or 12 years old instead of a 18 year old that can't grow up. So her body is aging normally meaning her hormones are fuctional...which leads to lulz harem like moments. She was still "crafted" in some sense of the word due to Holy Grail still being present.
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