And the time when Ino admires Shikamaru while talking to Chouji when Shikamaru is battling Temari. You can see her eyes sparkle.
Episode 64 05:17 - 05:46 might be a good example. (anbu&aone version)
I'm sure there are plenty more but I can't think of any now. I'm going to write down any pairing hintings I can find when I start my Naruto marathon when Naruto reaches episode 100.
Oh, and I want to see Shikamarus 16 hit combo that Ino mentions 2 times :P It sounds kickass. I can imagine him kicking people's ass tekken style