the only one I can think that hasn't been mentioned of is Touch. the first 13 or 26 episodes (i forgot...) are pretty boring, but its all set-up for the rest of the show.
nanoha definitly gets better as it goes on. The same (for me, at least) goes for stuff like azumanga, school rumble... once you get to know the characters better, it's a lot more funny and enjoyable.
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