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Lint is already a Brave Saint as it was shown that she was a reincarnated angel in Volume 24 in the Rias vs Vali match.
For Verrine, it said that evil pieces can't work on gods or god-class beings. Verrine being a Super Devil and defeating Mahabali and his team of Asuras along with Balberith just closes off the possibility of her becoming Issei's or anyone's servants.
Yes there's Issei but Rias reincarnated him into a devil before he became able to defeat god-class beings. And now we see the affect that is having on Issei's pawn pieces as all of them mutated.
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