Skies of Arcadia - Very atmospheric, ship battle theme fits it perfectly, boss theme that changes based on how well you're doing.
Tales of Legendia - Some very unique tracks, especially the one that plays in the very first area, have never heard anything like it in any other game in the series.
Star Ocean 3 - Great techno tracks, and of course Mission to Deep Space.
Xenosaga 3 - Some of the most epic boss battle themes ever.
Lost Odyssey - Just great all around, I like the map theme quite a bit.
Final Fantasy VI - I still think this is my favorite boss battle theme to this day, the second overworld theme is great as well.
Honorable mentions - Chrono Trigger, Secret of Mana
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