Dunno man, Saki was more in love with an idealized Shun and ignored (like a lot of viewers) who he was. As for the other way around, Shun has shown a lot more affection and care for Satoru, then Saki.
Nonetheless, because of Shun, Satoru/Saki dynamic is extremely interesting... and that is not the only couple she tried to spoil
That said, I am more intrigued about Maria because of Saki's early foreshadowing back in ep.2
Oh! and let's not forget about her brother... though with this stellar direction and anime writing, I don't have high hopes
